Environmental monitoring and measurements are
helpful in environmental assessments , as well as in many circumstances in
which human activities carry a risk of harmful effects on the environment. All
monitoring strategies and programs have reasons and justifications which are
often designed to establish the current status of an environment or to
establish trends in environmental parameters. Knowledge gained from this
information can be used to implement corrective and preventive action. Key
characteristics are those that the organization needs to consider to determine
how it is managing its significant environmental aspects, achieving objectives
and targets, and improving environmental performance. In order to ensure valid
results, measuring equipment should be calibrated or verified at specified
intervals, or prior to use, against measurement standards. Refer ISO 14001:2004
Clause 4.5.1
Sampling
Techniques
There are a various methods of sampling which
depend on the type of environment, industrial processes, the material being
sampled and the subsequent analysis of the sample. It is sometimes as simple as
filling a clean bottle with waste water and submitting it for conventional
chemical analysis and complex using electronic sensing devices taking
sub-samples over fixed or variable time periods and computing them to come out
at end results with the help of instruments and equipments
GRAB
SAMPLING
Grab samples are samples taken of a homogeneous
material, usually waste water, in a beaker or sample bottles. Grab samples
provide a good snap-shot view of the quality of the sampled waste water at the
point of sampling and at the time of sampling. Without additional monitoring,
the results cannot be extrapolated to other times or to other parts of the
waste water or ground-water. One should ensure that the grab sample must be the
representative sample of the water body. Grab samples are more appropriate for
small plants with low flows and limited staffs who cannot perform continuous
sampling. Grab samples do provide an immediate sample, and are thus to be
preferred for some tests such as pH, dissolved oxygen, total residual chlorine.
Composite
Sampling
It is a fact that sometimes mixing two or more
grab samples may not result in average of the characteristics of the waste
water samples. Chemical reactions can take place in mixed samples which alter
pH and chlorine residual values. Composite sampling is also known as an
integrated sampling which consists of a mixture of several individual grab
samples collected at regular and specified time periods, each sample taken in
proportion to the amount of flow at that time. Composite samples give a more
representative sample of the characteristics of water at the plant over a
longer period of time. The benefit of composite sampling is their ability to
take into account changes in flow and other characteristics of the water/waste
water over a period of time. This helps the sampling team to gain an overall picture
of the total effects that the influent will have on the treatment process and
that the effluent will have on the receiving water. However, composite samples
cannot be used for tests of water characteristics which change during storage
such as dissolved gases or of water characteristics which change when samples
are mixed together such as pH.
Monitoring
locations and Parameters
Predominant wind direction plays an important
role in determining location of monitoring stations. Due to effects such as
land and sea breezes, valley effects etc. it is important to collect local
meteorological data specific to the site. The monitoring stations should be
located in areas that are downwind from the sources. Mixing height data should
also be collected. Mixing height data can be collected from Indian
Meteorological Department.
Information on duration of various seasons in
a year is also important. Measurement frequency should be such that monitoring
is done in all the seasons so that all seasonal variations are included in
computing annual average. Parameters such as Sulphur Dioxide (SO2), Oxides of
Nitrogen as NO and Suspended Particulate Matter (SPM) and Respirable Suspended
Particulate Matter (RSPM/PM10), toxic
trace metals, Hydrogen Sulphide (H2S), Ammonia (NH3), and Polycyclic Aromatic
Hydrocarbons (PAHs) are monitored in Ambient Air.
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